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From
Review on 4-Hydroxycoumarin Chemistry: Synthesis, Acylation and Photochemical Properties
Jules Yoda, Abdoulaye Djandé, Lamine Cissé, Akoun Abou, Léopold Kaboré, Adama Saba
World Journal of Organic Chemistry
.
2019
, 7(1), 19-30 doi:10.12691/wjoc-7-1-4
Figure 1
. Numbered structure of 4-hydroxycoumarin
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Figure 2
. Tautomeric forms of 4-hydroxycoumarin
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Figure 3.
4-hydroxycoumarin synthesis routes
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Figure 4.
Compound 1: Synthesis by Pechman reaction
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Figure 5.
Compound 1: Synthesis using Meldrum’s acid
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Figure 6.
Compound
1:
synthesis using 2’-hydroxyacetophenone
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Figure 7
. Compound
1:
formation by condensation of 1-(2-hydroxyphenyl)ethanone
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Figure 8
. Compound
1 :
formation
using 4-acyl-3-hydroxycoumarin and 4-coumarinyl carboxylate
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Figure 9
. Compound
1:
formation by cleavage reaction
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Figure 10
. Compound
1:
formation by deacylation reaction
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Figure 11
. Compound
1
formation by decarboxylation reaction
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Figure 12
. Compound
1:
formation by photooxygenation of chromone-2-carboxylic Acid
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Figure 13.
Mesomeric equilibrium between alcoholate anion and carbanion from 4-hydroxycoumarin
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Figure 14.
3-acyl-4-hydroxycoumarin synthesis under ultrasound
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Figure 15.
Formation of 3-acyl-4-hydroxycoumarin with R= Alkyl or aryl
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Figure 16
. Formation of 3-formyl-4-hydroxycoumarin
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Figure 17.
Formation of 3-acetyl-4-hydroxycoumarin
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Figure 18.
Formation of 3-acetyl-4-hydroxycoumarin via acetate of 4-coumarinyl
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Figure 19
. Formation of 3-acetyl-4-hydroxycoumarin using phosphorous oxychloride
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Figure 20.
Microwave synthesis of
O
-acylated 4-hydroxycoumarin derivatives
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Figure 21.
Carboxylate of 4-coumarinyl synthesis using HSAB theory
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Figure 22
. Ortep structure of compound of
27b
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Figure 23.
Ortep structure of compound
27c
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Figure 24.
Ortep structure of compound of
27e
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Figure 25
. Ortep structure of compound of
27d
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Figure 26.
Structure of compound
28
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Figure 27
. Structure of compound
29
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Figure 28
. Structure of compound
30
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Figure 29.
Fluorescence emission of compound
27e
in acetonitrile
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