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From
Solvent Effects on the [3+2] Cycloaddition of 2-Furfural Oxime and Ethyl Propiolate: Unexpected Change in Regioselectivity
Promi Rahman, Amy Glanzer, Jaffarguriqbal Singh, Nanette M. Wachter, Jonathan Rhoad, Richard W. Denton
World Journal of Organic Chemistry
.
2017
, 5(1), 6-10 doi:10.12691/wjoc-5-1-2
Table 1. The effect of solvent polarity on the ratio of the 1,3-cycloaddition products 12 and 13
Full size table and legend
Table 2. The B3LYP/6-31G+(d) relative energies (ΔEa/ kcal/mol) and dipole moment change (D) of the transition states (TS-3,5 & TS-3,4) and products (12 & 13) in the gas phase, DMSO and dichloromethane
Full size table and legend