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From
Photoreforming of Biomass - Producing Hydrogen from Sugar
Julian Venzlaff, Claudia Bohrmann-Linde
World Journal of Chemical Education
.
2021
, 9(4), 130-135 doi:10.12691/wjce-9-4-5
Fig
ure
1.
Schematic representation of the processes in a photocatalyst. a. light excitation, b. electron-hole-pair, c. redox reactions at the activated semiconductor
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Fig
ure
2
.
Simplified schematic representation of the photoreforming process of glucose
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Fig
ure
3
.
a. driving out dissolved gas from the glucose solution by heating, b. adding glucose solution in the glass vessel with the Pt/TiO
2
-photocatalyst, c. closing the vessel with a pierced plug and cover, d. placing the glass vessel with the suspension into the pneumatic bath and a syringe without piston and a two-way stopcock on its top, e. filling the first syringe with water with the aid of a second syringe, f. irradiation of the substrate/photocatalyst suspension
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Fig
ure
4
.
Set-up of the detonating gas test. a. inserting 1 mL of the gas mixture in a soap solution, b. igniting the gas mixture
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Fig
ure
5
.
The peak caused by the collected gas appears after the same retention time as that of a control portion of hydrogen from a gas bottle
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Fig
ure
6
.
Volume of the collected gas during the photoreforming of glucose
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