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From
Hello Future! Printed Electronics as a Hands-On Experiment for Science Teaching
Lena Halbrügge, Amitabh Banerji, Sven Rösler
World Journal of Chemical Education
.
2021
, 9(4), 104-110 doi:10.12691/wjce-9-4-2
Figure 1.
Scheme of a printed electroluminescent device
Full size figure and legend
Figure 2.
Placing the substrate and sieve into the printing-machine (left) and optical detection of the markers for calibration (right)
Full size figure and legend
Figure 3.
Screen-printer with rubber blade during printing process (left) and professional UV-chamber for curing (right)
Full size figure and legend
Figure 4.
Fabrication steps for the hand-printed EL-device
Full size figure and legend
Figure
5
.
a) Band model of ZnS. In the ground state electrons are located in the valance-band (VB), whereas the conduction-band (CB) is empty.b) Band model of copper doped zinc sulfide (ZnS:Cu) with activator-level (AL) and coactivator-level (CL). In the ground-state electrons are located in the VB and AL, whereas the CB and CL are empty. c) During electroluminescence electrons are injected into the CB and get trapped in the CL. Simultaneously, the electrons from the VB are extracted, leaving a hole (i.e. a positive charge) behind. These holes get trapped in the AL.d) When trapped electrons on the CL encounter trapped holes on the AL, the charge carriers recombine under emission of visible light
Full size figure and legend
Figure
6
.
Structure-model derived from the flipped device. The insulating varnish is neglected in the structure-model for simplification. The Cu
2
S-crystallites (brown ellipses) have a narrow band-gap (see band-model in the upper right corner) and play a vital role for the bipolar injection mechanism
Full size figure and legend
Figure
7
.
a) Charge carriers are released from Cu
2
S-crystallites into the semiconductor layer due to the high electric field. b) Charge carriers move towards the electrodes and get captured in the traps of the semiconductor. c) Phase change of alternating current inverts the direction of the bipolar injection. The injected charge carriers encounter trapped ones with opposite charge. d) Trapped electrons and holes recombine under light emission
Full size figure and legend