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From
Short Communication: Electrochemiluminescence on the Basis of tris(bipyridyl)ruthenium(II) – Further Analytical Experiments
A. Habekost
World Journal of Chemical Education
.
2016
, 4(3), 64-66 doi:10.12691/wjce-4-3-3
Fig
ure
1
.
Left: Screen-printed electrodes with photomultiplier tube. Right: Modified ECL cell; at the bottom of the cell are the screen-printed electrodes
Full size figure and legend
Fig
ure
2
.
Top: Concentration-dependence of the ECL signal of three amino acids. The background (only Ru(II)) is quite low. Bottom: ECL intensity of proline (and Ru(bpy)
3
2+
) at low concentrations
Full size figure and legend
Fig
ure
3
.
Top: Detection of the absorption of the proline-ninhydrine complex (different proline concentrations) at 420 nm. Bottom: Absorption vs. concentration
Full size figure and legend
Fig
ure
4
.
ECL signal of glyphosate solution (10
-5
mol/L). Dashed red line: ECL of Ru(bpy)
3
2+
(background).
Full size figure and legend
Fig
ure
5
.
ECL intensity of 0.05 mol/L glyphosate solution without (760–800 s) and with (800–900 s) ZnO (1 mg) and with (900–960 s) TiO
2
(1 mg). Photomultiplier voltage: -1,200 V
Full size figure and legend