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From
Spectroscopic and Electrochemical Investigations of N-(Phosphonomethyl)glycine (glyphosate) and (Aminomethyl)phosphonic Acid (AMPA)
A. Habekost
World Journal of Chemical Education
.
2015
, 3(6), 134-140 doi:10.12691/wjce-3-6-2
Figure 1
.
left: Copper sheets in water with glyphosate (left) and with AMPA (right); Right: Copper sheets in sodium carbonate with glyphosate (left), with AMPA (right), and without glyphosate or AMPA (middle)
Full size figure and legend
Figure 2
.
Spectra of Cu-glyphosate and Cu-AMPA
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Figure 3
.
CuO in sodiumcarbonate, Cu in sodiumcarbonate, Cu in KOH, and Cu in H
2
O after 12 hours, respectively
Full size figure and legend
Figure 4
.
Titration of glyphosate and AMPA
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Figure 5
.
Titration of Weed killer
®
and Roundup
®
compared to pure glyphosate
Full size figure and legend
Figure 6
.
FTIR ofglyphosate (top) and AMPA (bottom)in a KBrpellet
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Figure 7
.
FTIR of glyphosate (black), Cu-glyphosate after 10 minutes (red), and Cu-glyphosate (green line) after 12 hours
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Figure
8
.
FTIR spectrum of AMPA (black) and Cu-AMPA (red)
Full size figure and legend
Figure 9
.
I: GC spectra of the glyphosate derivate C, A: AMPA (contamination of the injection syringe), and B: glyphosate fragment m/z 464; II: GC and EI-mass spectrum of the AMPA derivate; III: GC-MS spectrum of both AMPA and glyphosate derivates simultaneously
Full size figure and legend
Figure 10
.
GC-MS spectrum of Roundup
®
—glyphosate peakC at about eightminutes
Full size figure and legend
Figure 11
.
Cyclic voltammograms of copper sulfate after deposition of copper (red, dotted curves) and of copper sulfate / glyphosate mixture (same conditions).Only the anodic curves are shown. The arrows indicate increase of the CV scan
Full size figure and legend
Figure
12
.
Extraction equipment: heater, flask, Soxhlet with extraction thimble containing glyphosate and soil, and the reflux cooler
Full size figure and legend