Figure 4. A single cycle taken from Figure 3. The dashed vertical line marks the voltage turning point at -1.5 V (90 s). The solid vertical lines mark the onsets (from left to right) of reactions 1 (colorless to blue), 2 (blue to yellow), 3 (yellow to blue), and 6 (blue to colorless). The novice might need to be alerted to the fact that the potentials at which the color changes start to happen do not correspond to the peak-current potentials in the CV. The CV peak-current potentials show at which potential the reactions are most efficient, not the ones at which they can start to occur

From

Electrochromism of Methylviologen (Paraquat)

N. Aristov, A. Habekost

World Journal of Chemical Education. 2015, 3(4), 82-86 doi:10.12691/wjce-3-4-1