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From
Low-field NMR Spectroscopy in Chemical Education
Marcel Emmert, Ekkehard Geidel
World Journal of Chemical Education
.
2023
, 11(3), 45-53 doi:10.12691/wjce-11-3-5
Figure
1
.
Experimental setup for the fermentation process
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Figure
2
.
Determination of the ethanol concentration as a weight fraction in a sample of vodka by comparing signal intensities [3]
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Figure
3
.
Selected
1
H-NMR spectra (60 MHz) of the fermenting apple juice with signal assignments
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Figure
4
.
Progress of the fermentation reaction of apple juice
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Figure
5
.
Comparison of a 400 MHz (above) and a 60 MHz (below)
1
H-NMR-spectrum of a Mirabelle plum brandy that contains maleic acid as an internal standard. The integrals show the intensities of the signals of the protons of maleic acid (δ = 6.3 ppm; vinyl protons), water (and the hydroxy groups of the alcoholic compounds at δ = 4.8 ppm), the methyl group of methanol (δ = 3.3 ppm) and the methyl group of ethanol (δ = 1.1 ppm) [3].
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Figure
6
.
S
N
1-
m
echanism
for
the
reaction
of
tert-Butyl
chloride
with
water
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Figure
7
.
1
H-NMR spectrum of the reaction mixture, 29 minutes after the start of the reaction at 10°C
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Figure
8
.
Obtained signal intensities of the methyl-protons of tert-Butyl chloride in dependence on time for the reaction at 20°C
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Figure
9
.
Comparison of
1
H-NMR-spectra of the reaction mixture in protonated (red spectrum) and deuterated (blue spectrum) solvent mixtures
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Figure
10
.
1
H-NMR spectra over time of the hydrolysis of 2-Chloro-2-methylpropane at 10 °C, recorded via a reaction monitoring kit
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