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Figures index
From
Structure, Melting and Transport Properties of Binary Liquid Pd-Si Metal Alloys: Molecular Dynamics Simulations
Muhammad Faruq, Antoine Villesuzanne, Meilan Guo, Guosheng Shao
Journal of Materials Physics and Chemistry
.
2017
, 5(1), 20-31 doi:10.12691/jmpc-5-1-3
Fig
ure
1
. FCC based Pd (a =3.9382 Å & No of atoms in unit cell -4) and Si closed packed (a=3.7653 Å & No of atoms in unit cell -4) crystal structures
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Fig
ure
2.
Equation of state for Pd-Si
FCC
alloys: comparison between Quantum Sutton-Chen, Embedded atom (EAM) from ref. [39] and DFT calculations
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Fig
ure
3.
Density (a) and enthalpy (b) during heating for Pd
FCC
, Si
Diamond
and Pd-Si
ICSD
alloys during heating at 5 K/ps. Note: ICSD represents structure from “the Inorganic Crystal Structure Database”
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Fig
ure
4.
Calculated and experimental melting temperature of Pd-Si system with experimental result taken from Ref. [52]
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Fig
ure
5
. Slab Pd
3
Si supercell based on Pd
3
Si
ICSD
unit cell (Super cell a = 23.47 Å, b = 30.53Å & c = 21.31 Å, Slab Box size =70.32 x 30.53 x 21.31, No of atoms in super cell -1024)
Full size figure and legend
Fig
ure
6.
The change in cohesive energy a) and bond orientational order parameter, Q
6
b) during heating the slab model of Pd
3
Si alloy
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Fig
ure
7.
Pair correlation function for different phases of PdSi alloy during heating and cooling at 10 K/ps
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Fig
ure
8.
Pair correlation function of Pd
3
Si
ICSD
alloy at different temperatures: Total pair correlation function (a); and partial pair correlation functions for Pd-Pd (b), Si–Si (c) and Pd–Si (d)
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Fig
ure
9.
Snapshot of atomic structure for Solid state (a) (the crystalline structure has regular pattern), liquid state (b) (crystal structure has short range order)
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Fig
ure
10.
Pair correlation function of Pd-Si
ICSD
alloys at the melting temperature
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Fig
ure
11.
Average mean square displacement vs time at different temperatures near the melting point, for (a) SiFCC, (b) Pd, and (c) PdSi alloy
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Fig
ure
12.
Diffusion coefficient vs composition in Pd-Si
ICSD
alloys at and near the melting point (MP)
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Fig
ure
13
.
Arrhenius plot of diffusion coefficients for Pd, computed from the Einstein relation
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