, Mariam D. Solomon2, Jaryum H. Kiri2, Jonathan D. Dabak2, Samuel Y. Gazuwa2, Simon G. Mafulul2, Raymond I. Daspan3, Elizabeth O. Okoh4, Isaac S. Laka5, Jane-Rose Onche2, Isa S. Wuti21Department of Physics, University of Jos, Plateau State-Nigeria
2Department of Biochemistry, University of Jos, Plateau State-Nigeria
3Department of Geology, University of Jos, Plateau State-Nigeria
4Department of Community Medicine, University of Jos, Plateau State-Nigeria
5Department of Geography, University of Jos, Plateau State-Nigeria
Background: When stones are crushed, the finer dust gets airborne and escapes as fugitive emissions, constituting dust pollution problems in the vicinity with severe adverse effects on the ambient air quality and human health. Methodology: In this study, active sampling method was deployed to sample and obtain the ambient concentrations of CO, SO2, H2S and PM (of sizes 2.5 and 10 microns) in the fugitive emissions from selected manual stone crushing sites in North Central Nigeria. The trapped particles sampled were analysed for particulate-associated heavy metals such as Cd, Co, Cr, Cu, Pb, Mn, Ni, Fe, and Zn by Atomic Absorption Spectrometry (AAS). Principal Findings: The observed mean concentration of CO, SO2 and H2S sampled were 0.12 mg/m3, 0.06 mg/m3 and 0.004 mg/m3, respectively. The mean concentration of PM2.5 was observed to be 26.5 µg/m3 (ranged from 8 µg/m3 to 70 µg/m3) which is about 76.7 % higher than the World Health Organization (WHO) air quality guidelines (15 µg/m3 for 24- mean for PM2.5). The Mean concentration of PM10 was observed to be 54.36 µg/m3 (ranged from 17 µg/m3 to 143 µg/m3) which is about 20.8 % higher than the World Health Organization (WHO) air quality guidelines (45 µg/m3 for 24-mean for PM10). AAS analysis revealed that metal- bearing particulates have significant levels of the selected heavy metals except copper that was below detection limit: Cr, Mn, Fe, Pb, Zn, Ni, Cd and Co were respectively, 48.0 mg/m3, 82.0 mg/m3, 140.0 mg/m3, 202.0 mg/m3, 34.0 mg/m3, 1403.0 mg/m3, 21.0 mg/m3, 60.0 mg/m3. Conclusion: All the metals (Pb, Ni and Cd), classified by IARC as carcinogenic in humans (group 1) greatly exceeded on average the annual EU’s limits (500, 20, 6 and 5 ng/ m3 respectively).
| [1] | Adar, S.D.; Filigrana, P.A.; Clements, N.; Peel, J.L. Ambient Coarse Particulate Matter and Human Health: A Systematic Review and Meta-Analysis. Curr. Environ. Health Rep. 2014, 1, 258-274.View Article |
| [2] | Bell, M.L.; Ebisu, K.; Peng, R.D.; Walker, J.; Samet, J.M.; Zeger, S.L.; Dominici, F. Seasonal and regional short-term effects of fine particles on hospital admissions in 202 US Counties, 1999–2005. Am. J.Epidemiol. 2008, 168, 1301-1310.View Article |
| [3] | Hänninen, O.; Knol, A.B.; Jantunen, M.; Lim, T.A.; Conrad, A.; Rappolder, M.; Carrer, P.; Fanetti, A.C.; Kim, R.; Buekers, J.; et al. Environmental burden of disease in Europe: Assessing nine risk factors in six countries. Environ. Health Perspect. 2014, 122, 439-446.View Article |
| [4] | Héroux, M.E.; Anderson, H.R.; Atkinson, R.; Brunekreef, B.; Cohen, A.; Forastiere, F.; Hurley, F.; Katsouyanni, K.; Krewski, D.; Krzyzanowski, M.; et al. Quantifying the Health Impacts of Ambient Air Pollutants: Recommendations of a WHO/Europe Project. Int. J.Public Health 2015, 60, 619-627.View Article |
| [5] | Hoek, G.; Krishnan, R.M.; Beelen, R.; Peters, A.; Ostro, B.; Brunekreef, B.; Kaufman, J.D. Long-term air pollution exposure and cardio-respiratory mortality: A review. Environ. Health 2013, 12, 43.View Article |
| [6] | World Health Organization (WHO). Ambient Air Pollution: A Global Assessment of Exposure and Burden of Disease; World Health Organization: Geneva, Switzerland, 2016; 121p, ISBN 978 92 4 151135 1. |
| [7] | Himanshu M. Padhy, Pranati Mishra, Sadasiba Rout and Babita Kumari.2020, Dust Pollution in Stone Crusher Units in and Around Khurda, Orissa, India. Int J Recent Sci Res. 11(05), pp. 38705-38708. |
| [8] | Sivacoumar R.; Jayabalou R.; Swarnalatha S.; and Balakrishnan K., (2014). Particulate Matter from Stone Crushing Industry: Size Distribution and Health Effects. Occupational Safety; Health Hazards: India. 10:1061/(ASCE)0733-9372(2006)132:3(405).View Article |
| [9] | Chougule A.C., Chougule P.A., Kumbhoje C.K. (2017). Effect of Stone Crusher on Ambient Air Quality. International Research Journal of Engineering and Technology (IRJET). Volume: 04 Issue: 07. |
| [10] | Mathur, M.L., and Choudhary R.C. (1996). “Mortality experience of sand stone quarry workers of Jodhpur district.”Lung India, XIV(2), 66-68. |
| [11] | Central Pollution Control Board (CPCB). (1998). “National ambient air quality standards. Air (Prevention and Control of Pollution) Act S.O.384(E), New Delhi, India. |
| [12] | Romanazzi, V.; Casazza, M.; Malandrino, M.; Maurino, V.; Piano, A.; Schilirò, T.G.; Gilli, G. PM10 size distribution of metals and environmental-sanitary risk analysis in the city of Torino. Chemosphere 2014, 112, 210–216. [CrossRef] [PubMed].View Article |
| [13] | Li, H.; Wang, J.; Wang, Q.G.; Qian, X.; Qian, Y.; Yang, M.; Li, F.; Lu, H.; Wang, C. Chemical fractionation of arsenic and heavy metals in fine particle matter and its implications for risk assessment: A case study in Nanjing, China. Atmos. Environ. 2015, 103, 339-346.View Article |
| [14] | Lyu, Y.; Zhang, K.; Chai, F.; Cheng,T.; Yang, Q.; Zheng, Z.; Li, X. Atmosphericsize-resolvedtraceelementsin a city affected by non-ferrous metal smelting: Indications of respiratory deposition and health risk. Environ. Pollut. 2017, 224, 559-571.View Article |
| [15] | Pinto, E.; Soares, C.; Couto, C.M.; Almeida, A. Trace Elements in Ambient Air at Porto Metropolitan Area-Checking for Compliance with New European Union (EU) Air Quality Standards. J. Toxicol. Environ. Health A 2015, 78, 848-859.View Article |
| [16] | Samek, L. Overal human mortality and morbidity due to exposure to air pollution. IJOMEH 2016, 29, 417-426.View Article |
| [17] | Singh, D.K.; Gupta, T. Source apportionment and risk assessment of PM1 bound trace metals collected during foggy and non-foggy episodes at a representative site in the Indo-Gangetic plain. Sci. Total Environ. 2016, 550, 80-94.View Article |
| [18] | Niu, L.; Ye, H.; Xu, C.; Yao, Y.; Liu,W. Highly time-and size resolved finger print analysis and risk assessment of airborne elements in a megacity in the Yangtze River Delta, China. Chemosphere 2015, 119, 112-121.View Article |
| [19] | Bello, S.; Muhammad, B.G.; Bature, B. Total Excess Lifetime Cancer Risk Estimation from Enhanced Heavy Metals Concentrations Resulting from Tailings in Katsina Steel Rolling Mill, Nigeria. J. Mater. Sci. Eng. 2017, 6, 338. |
| [20] | Benhaddya, M.L.; Boukhelkhal, A.; Halis, Y.; Hadjel, M. Human health risks associated with metals from urban soil and road dust in an oilfield area of South eastern Algeria. Arch. Environ. Contam. Toxicol. 2016, 70, 556-571.View Article |
| [21] | IARC (2015). Outdoor Air Pollution: IARC Monographs on the Evaluation of Carcinogenic Risks to humans 2015; 109: 35-109. |
| [22] | Yadav, I.C.; Devi, N.L.; Singh, V.K.; Li, J.; Zhang, G. Spatial distribution, source analysis, and health risk assessment of heavy metals Contamination in house dust and surfaces oil from four major cities of Nepal. Chemosphere 2019, 218, 1100-1113.View Article |
| [23] | Macleod, W.N., Turner, D.C., and Wright, E.P. (1971): The Geology of Jos-Plateau, Vol.1 General Geology. Geol. Surv. Of Nigeria. Bul1 No 32. |
| [24] | Turner, M.G. (1989). Landscape Ecology: The Effect of Pattern on Process. Annual Review of Ecology and Systematics, 20, 171-197.View Article |
| [25] | Seinfeld JH, Pandis S (2006). Atmospheric chemistry and physics. 2nd ed. Hoboken (NJ): John Wiley. |
| [26] | World Health Organization (WHO). Health Risks of Particulate Matter from Long-Range Transboundary Air Pollution; WHO Regional Office for Europe, 2006. |
| [27] | Brauer M, Amann M, Burnett RT, Cohen A, Dentener F, Ezzati M et al. (2012). Exposure assessment for estimation of the global burden of disease attributable to outdoor air pollution. Environ Sci Technol, 46(2): 652-60.View Article |
| [28] | Tang,R.; Ma, K.; Zhang ,Y .; Mao ,Q. The spatial characteristics and pollution levels of metals in urban street dust of Beijing, China. Appl. Geochem. 2013, 35, 88-98.View Article |
| [29] | Andrea Geiger and John Cooper, Draft APPENDIX C- Overview of Airborne Metals Regulations, Exposure Limits, Health Effects, and Contemporary Research. 2010. |
| [30] | Schauer JJ, Lough GC, Shafer MM, Christensen WF, Arndt MF, DeMinter JT et al. (2006). Characterization of metals emitted from motor vehicles. Res Rep Health Eff Inst, 133(133): 1-76, discussion 77-88. |
| [31] | Snyder DC, Schauer JJ, Gross DS, Turner JR (2009b). Estimating the contribution of point sources to atmospheric metals using single-particle mass spectrometry. Atmos Environ, 43(26): 4033-42.View Article |